How to Safely Use Lye for Pretzels (2024)

Ditch the baking soda and learn how to make pretzels the old-fashioned way—by using a lye bath.

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If you’ve ever wondered how to achieve that classic, deeply golden sheen on homemade pretzels, this article is for you. I’m talking about how to safely work with lye for pretzels.

Fair warning, you’re going to need to be adventurous, willing to purchase a slightly hazardous chemical and wear some personal protective equipment. It may sound scary, but this method will transform your homemade pretzels from good to glorious.

What Is Lye?

Lye—also known as sodium hydroxide—is an alkaline compound often used to make household cleaners, soap and detergents. It’s also used to provide authentic Bavarian-style pretzels with that golden color, rich flavor and sheen.

Lye affects the baking process in pretzels by speeding up the Maillard reaction that occurs on the outside of the pretzels as they bake. For baking newbies, the Maillard reaction is a chemical reaction that happens between the amino acids and sugars in bread dough that gives bread products their color while also imparting flavor.

You can achieve similar pretzel results with this trick using baked baking soda—but a lye solution is best.

Safety Tips for Baking Pretzels with Lye

The most important thing you need to know about lye is that it can be dangerous. As a caustic substance, when used or mixed improperly, lye can cause severe burns to bare skin, cause permanent eye damage and discolor working surfaces. Here are a few tips to keep you and your kitchen safe when working with lye.

Wear Personal Protective Equipment

Safety first! We advise wearing long sleeves and protective rubber or disposable gloves when working with lye. (Make sure you know how to safely remove gloves.) Wear closed-toe shoes and protective eye equipment to keep yourself safe from spills or splashes, too.

Finally, work in a well-ventilated space. Turn on your range hood’s fan or open a window, since inhaling sodium hydroxide can be hazardous if safety precautions are not taken.

Use Proper Mixing Equipment

A lye solution should not be mixed in just any container with just any spoon. When working with lye, you’ll want to use a non-reactive bowl since lye is caustic. We recommend a heavy, plastic container to be extra safe.

We do not recommend using glass or metal containers made from aluminum to mix a lye solution. Lye can etch (even Pyrex) over time and cause it to shatter and lye can (and will) dissolve aluminum, so do not mix the two.

Editor’s Tip: Not all plastics are created equal. The best way to know if your container is safe for mixing lye, check the recycling symbol and number printed on the container (typically on the bottom). A container labeled #2 (high-density polyethylene; HDPE) or #5 (polypropylene; PP) are best.

Protect Surfaces

As stated earlier, lye is caustic. It can damage or discolor certain materials, like butcher block and natural stone surfaces. Better safe than sorry, so lay down a plastic cutting board or pastry slip mat to protect those fancy marble countertops!

Dispose of Leftover Lye Safely

Keep a few rags handy to wipe up drips or spills immediately. Don’t wait till you’re done. When you finish dipping pretzels into the lye bath, pour any leftover solution down the drain of your kitchen sink. We recommend doing so with the cold water running.

As an extra precaution, to neutralize any lingering lye solution, pour a bit of vinegar down your drain and wipe your counters with a vinegar-soaked rag.

How to Make a Lye Bath for Pretzels

In many modern pretzel recipes (like this Chewy Soft Pretzel recipe), there will typically be a step that involves bringing a mixture of water and baking soda to a boil. The recipe will direct you to place the shaped, unbaked pretzels, one at a time, in the boiling water for a few seconds prior to baking.

When opting to use lye for pretzels, skip that step and replace it with the following process:

Step 1: Combine lye with cold water

To prepare a lye bath for pretzels, fill a large liquid measuring cup with four cups of cold water. Add the water to a heavy, plastic container and carefully mix with two tablespoons of food-grade lye until fully dissolved.

Editor’s Tip: Sodium hydroxide (lye) produces an exothermic reaction (which means it gets hot) when combined with water. Starting with ice-cold water ensures the lye solution remains at a safe temperature for handling.

Step 2: Dip the pretzels

Once your lye bath is properly mixed, carefully lower your unbaked pretzels into the solution for 10 to 15 seconds, then remove to a parchment-lined baking sheet. Bake as directed by your recipe.

Editor’s Tip: We like to use a heat-resistant, non-reactive stainless steel deep fryer spider to dip the pretzels into the solution.

Where to Buy Food-Grade Lye

Food-grade lye isn’t something you’ll find at most grocery stores, but it’s readily available on Amazon and sometimes at specialty baking retailers or restaurant supply stores.

Tools You’ll Need

How to Safely Use Lye for Pretzels (2024)

FAQs

Is it safe to use lye for pretzels? ›

As long as you follow some straightforward guidelines, it's perfectly safe to use lye in your home kitchen. With the right equipment, the proper precautions, and an understanding of the dangers involved, you'll be churning out pretzels and bagels safely in no time. Before you start, make sure you have the right gear.

How to use lye when making pretzels? ›

Carefully sprinkle the lye into the water. Use a heat-safe silicone spatula to carefully stir the lye to dissolve. The lye is dissolved when the water looks clear (the container will feel warm to the touch – this is normal). Dip a shaped pretzel into the lye bath for about 30 seconds.

How to use lye safely? ›

Making Soap with Lye: 7 Must-Know Safety Rules
  1. Use Only 100% Lye. ...
  2. Wear Gloves and Protective Goggles. ...
  3. Always Pour Lye Into Water, NEVER the Other Way Around. ...
  4. Don't Use Aluminum Pots or Utensils. ...
  5. Use Heat-Safe Plastic Containers for the Lye water Mixture (Not Glass) ...
  6. Use Cold Water. ...
  7. Set Your Lye Water Container in the Skin.

What are the side effects of lye in food? ›

Sodium hydroxide is a potentially dangerous substance. It can hurt you if it touches your skin, if you drink it or if you breathe it. Eating or drinking sodium hydroxide can cause severe burns and immediate vomiting, nausea, diarrhea or chest and stomach pain, as well as swallowing difficulties.

What is a good substitute for lye in pretzels? ›

That is by taking baking soda, spreading it out on a baking pan and putting it into the oven at about 250-300 degrees Fahrenheit for about an hour. That changes the chemical properties in the baking soda to make it behave more similarly to lye.

Is lye in pretzels bad for your stomach? ›

Once lye-dipped pretzels are baked, they're totally safe (and delicious!) to eat. The most important aspect of baking with lye is that it's diluted, which greatly reduces (but doesn't eliminate) the risk of harm. Doughs are typically dipped in a solution made up of 3% to 4% (by weight) lye-to-water before baking.

What neutralizes lye? ›

It's true that vinegar can neutralize lye, but it generates heat as a by-product. This is called an exothermic reaction. You see, while lye is a strong alkaline, vinegar is a fairly weak acid.

Does Auntie Anne's use lye? ›

Well, the cheery ladies were very clear with me: they do NOT use lye. No sodium hydroxide/poison/caustic soda—none whatsoever—in their pretzels. (They do, however, dip their pretzels in a baking soda solution.) So there you have it.

Are bagels dipped in lye? ›

Well yes, lye can do that but did you also know it is used to make bagels? Some bakers will dip the bagel in a lye solution as it speeds up the process that creates the distinctive bagel crust and taste.

Is lye toxic to the body? ›

Lye water (sometimes called 'Lime Water') is a strong (caustic) liquid that is safe to use in very small amounts in cooking, but it can be dangerous if lye water is swallowed undiluted straight from the bottle. It can cause severe corrosive burns to the throat, oesophagus and stomach with permanent damage if swallowed.

What containers are safe for lye? ›

You need to measure your water and lye in two separate containers. Because of that exothermic reaction, we recommend glass, heat-resistant plastic, or stainless steel. Do not use tin or aluminum. It reacts with the sodium hydroxide and produces harmful fumes.

How to get lye off your skin? ›

Rinse with plenty of plain cool running water. Vinegar, an acid, does indeed neutralize NaOH or KOH, both bases, but there are serious downsides to doing this kind of chemistry directly on the body.

How much lye to use for pretzels? ›

In a deep bowl, wearing rubber or latex gloves, make a solution of ½ cup lye and 10 cups water (or 1 part lye to 20 parts water); pour lye carefully into water to avoid splashing. Dip each pretzel in solution, turning it over for 10 to 15 seconds, and place back on baking sheet.

What is a substitute for lye? ›

In this method, you're replacing lye with baking soda, both of which are alkalies. However, lye is much stronger than baking soda. Heating up baking soda in the oven turns it from sodium bicarbonate into sodium carbonate, making it a slightly stronger alkali that'll better replace the lye.

Is lye a carcinogen? ›

The Department of Health and Human Services (DHHS), the International Agency for Research on Cancer (IARC), and the U.S. Environmental Protection Agency (EPA) have not classified sodium hydroxide for carcinogenicity in humans.

Is lye ok to eat? ›

Lye water is a strongly alkaline (caustic) solution which can cause severe injury in the form of corrosive burns, especially to the throat, oesophagus and stomach if swallowed. These injuries can result in hospitalisation and permanent damage in severe cases.

Is sodium hydroxide safe in food? ›

The sodium hydroxide in our products is food-grade and designated as safe for general use in food by the FDA1. Sodium hydroxide has been widely used in drinking water as a pH adjusting agent and is also used in food processing.

Is lye safe in stainless steel? ›

Because of that exothermic reaction, we recommend glass, heat-resistant plastic, or stainless steel. Do not use tin or aluminum. It reacts with the sodium hydroxide and produces harmful fumes. A few makers have mentioned that their glass containers cracked or broke while mixing the solution.

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